Spatially resolved photocurrent mapping of efficient organic solar cells fabricated on a woven mesh electrode
Identifieur interne : 000514 ( Main/Repository ); précédent : 000513; suivant : 000515Spatially resolved photocurrent mapping of efficient organic solar cells fabricated on a woven mesh electrode
Auteurs : RBID : Pascal:13-0193168Descripteurs français
- Pascal (Inist)
- Courant photoélectrique, Mappage, Cellule solaire organique, Electronique organique, Dispositif photovoltaïque, Appareil portatif, Dispositif photovoltaïque intégré bâtiment, Matériau minéral, Couche ITO, Addition étain, Procédé revêtement, Procédé fabrication, Conversion énergie, Taux conversion, Tissu textile, Transducteur enfoui, Grille métallique, Contact électrique, Surface lisse, Evaluation performance, Silicium, Oxyde d'indium, Matériau conducteur, Matériau transparent, Thiophène dérivé polymère, Acide butyrique, Ester, Composé du fullerène, Fibre polymère, Couche mince, ITO, Procédé roll-to-roll.
English descriptors
- KwdEn :
- Building integrated photovoltaics, Butyric acid, Coating process, Conducting material, Conversion rate, Electric contact, Embedded transducer, Energy conversion, Ester, Fullerene compounds, ITO layers, Indium oxide, Inorganic material, Manufacturing process, Mapping, Metal grid, Organic electronics, Organic solar cells, Performance evaluation, Photoelectric current, Photovoltaic cell, Polymer fibers, Portable equipment, Roll-to-roll process, Silicon, Smooth surface, Thin film, Thiophene derivative polymer, Tin addition, Transparent material, Woven material.
Abstract
Flexible organic photovoltaic devices may soon find applications in various fields, such as portable electronics or building-integrated photovoltaics, occupying market niches that are currently not covered by the prevailing photovoltaic technology based on silicon and other inorganic materials. For these applications, there is an urgent need to replace the commonly used indium tin oxide by transparent and electrically conductive materials that can be processed cost-effectively by large-area compatible printing and coating processes. Here, we fabricated P3HT/PCBM organic solar cells with a power conversion efficiency of 3.1% on a flexible, transparent and conductive woven fabric electrode. The electrode is produced by a roll-to-roll process and consists of a polymer-embedded fibre/metal wire grid. Metal wires protrude as little as 5 μm from the electrode plane, providing electrical contact points on a smooth surface suitable for thin film deposition. The use of spatially resolved photocurrent mapping experiments showed a high level of detailed information, with the unexpected indication that there probably exists a maximum in the cell performance versus mesh size opening and that woven fabric electrodes with largest geometrical open area do not necessarily perform better.
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Pascal:13-0193168Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Spatially resolved photocurrent mapping of efficient organic solar cells fabricated on a woven mesh electrode</title><author><name sortKey="Kylberg, William" uniqKey="Kylberg W">William Kylberg</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Empa, Swiss Federal Institute for Materials Science and Technology, Laboratory for Functional Polymers, Überlandstrasse 129</s1><s2>8600 Dübendorf</s2><s3>CHE</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>8600 Dübendorf</wicri:noRegion></affiliation></author><author><name sortKey="Araujo De Castro, Fernando" uniqKey="Araujo De Castro F">Fernando Araujo De Castro</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>National Physical Laboratory, Hampton Road, Teddington</s1><s2>Middlesex TW11 0LW</s2><s3>GBR</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Royaume-Uni</country><wicri:noRegion>Middlesex TW11 0LW</wicri:noRegion></affiliation></author><author><name sortKey="Chabrecek, Peter" uniqKey="Chabrecek P">Peter Chabrecek</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Sefar AG, Freibach</s1><s2>9425 Thai</s2><s3>CHE</s3><sZ>3 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>9425 Thai</wicri:noRegion></affiliation></author><author><name sortKey="Geiger, Thomas" uniqKey="Geiger T">Thomas Geiger</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Empa, Swiss Federal Institute for Materials Science and Technology, Laboratory for Functional Polymers, Überlandstrasse 129</s1><s2>8600 Dübendorf</s2><s3>CHE</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>8600 Dübendorf</wicri:noRegion></affiliation></author><author><name sortKey="Heier, Jakob" uniqKey="Heier J">Jakob Heier</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Empa, Swiss Federal Institute for Materials Science and Technology, Laboratory for Functional Polymers, Überlandstrasse 129</s1><s2>8600 Dübendorf</s2><s3>CHE</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>8600 Dübendorf</wicri:noRegion></affiliation></author><author><name sortKey="Nicholson, Patrick G" uniqKey="Nicholson P">Patrick G. Nicholson</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>National Physical Laboratory, Hampton Road, Teddington</s1><s2>Middlesex TW11 0LW</s2><s3>GBR</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Royaume-Uni</country><wicri:noRegion>Middlesex TW11 0LW</wicri:noRegion></affiliation></author><author><name sortKey="N Esch, Frank" uniqKey="N Esch F">Frank N Esch</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Empa, Swiss Federal Institute for Materials Science and Technology, Laboratory for Functional Polymers, Überlandstrasse 129</s1><s2>8600 Dübendorf</s2><s3>CHE</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>8600 Dübendorf</wicri:noRegion></affiliation></author><author><name sortKey="Theocharous, Evangelos" uniqKey="Theocharous E">Evangelos Theocharous</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>National Physical Laboratory, Hampton Road, Teddington</s1><s2>Middlesex TW11 0LW</s2><s3>GBR</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Royaume-Uni</country><wicri:noRegion>Middlesex TW11 0LW</wicri:noRegion></affiliation></author><author><name sortKey="Sonderegger, Uriel" uniqKey="Sonderegger U">Uriel Sonderegger</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Sefar AG, Freibach</s1><s2>9425 Thai</s2><s3>CHE</s3><sZ>3 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>9425 Thai</wicri:noRegion></affiliation></author><author><name sortKey="Hany, Roland" uniqKey="Hany R">Roland Hany</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Empa, Swiss Federal Institute for Materials Science and Technology, Laboratory for Functional Polymers, Überlandstrasse 129</s1><s2>8600 Dübendorf</s2><s3>CHE</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Suisse</country><wicri:noRegion>8600 Dübendorf</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">13-0193168</idno><date when="2013">2013</date><idno type="stanalyst">PASCAL 13-0193168 INIST</idno><idno type="RBID">Pascal:13-0193168</idno><idno type="wicri:Area/Main/Corpus">000D20</idno><idno type="wicri:Area/Main/Repository">000514</idno></publicationStmt><seriesStmt><idno type="ISSN">1062-7995</idno><title level="j" type="abbreviated">Prog. photovolt.</title><title level="j" type="main">Progress in photovoltaics</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Building integrated photovoltaics</term><term>Butyric acid</term><term>Coating process</term><term>Conducting material</term><term>Conversion rate</term><term>Electric contact</term><term>Embedded transducer</term><term>Energy conversion</term><term>Ester</term><term>Fullerene compounds</term><term>ITO layers</term><term>Indium oxide</term><term>Inorganic material</term><term>Manufacturing process</term><term>Mapping</term><term>Metal grid</term><term>Organic electronics</term><term>Organic solar cells</term><term>Performance evaluation</term><term>Photoelectric current</term><term>Photovoltaic cell</term><term>Polymer fibers</term><term>Portable equipment</term><term>Roll-to-roll process</term><term>Silicon</term><term>Smooth surface</term><term>Thin film</term><term>Thiophene derivative polymer</term><term>Tin addition</term><term>Transparent material</term><term>Woven material</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Courant photoélectrique</term><term>Mappage</term><term>Cellule solaire organique</term><term>Electronique organique</term><term>Dispositif photovoltaïque</term><term>Appareil portatif</term><term>Dispositif photovoltaïque intégré bâtiment</term><term>Matériau minéral</term><term>Couche ITO</term><term>Addition étain</term><term>Procédé revêtement</term><term>Procédé fabrication</term><term>Conversion énergie</term><term>Taux conversion</term><term>Tissu textile</term><term>Transducteur enfoui</term><term>Grille métallique</term><term>Contact électrique</term><term>Surface lisse</term><term>Evaluation performance</term><term>Silicium</term><term>Oxyde d'indium</term><term>Matériau conducteur</term><term>Matériau transparent</term><term>Thiophène dérivé polymère</term><term>Acide butyrique</term><term>Ester</term><term>Composé du fullerène</term><term>Fibre polymère</term><term>Couche mince</term><term>ITO</term><term>Procédé roll-to-roll</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Flexible organic photovoltaic devices may soon find applications in various fields, such as portable electronics or building-integrated photovoltaics, occupying market niches that are currently not covered by the prevailing photovoltaic technology based on silicon and other inorganic materials. For these applications, there is an urgent need to replace the commonly used indium tin oxide by transparent and electrically conductive materials that can be processed cost-effectively by large-area compatible printing and coating processes. Here, we fabricated P3HT/PCBM organic solar cells with a power conversion efficiency of 3.1% on a flexible, transparent and conductive woven fabric electrode. The electrode is produced by a roll-to-roll process and consists of a polymer-embedded fibre/metal wire grid. Metal wires protrude as little as 5 μm from the electrode plane, providing electrical contact points on a smooth surface suitable for thin film deposition. The use of spatially resolved photocurrent mapping experiments showed a high level of detailed information, with the unexpected indication that there probably exists a maximum in the cell performance versus mesh size opening and that woven fabric electrodes with largest geometrical open area do not necessarily perform better.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1062-7995</s0></fA01><fA03 i2="1"><s0>Prog. photovolt.</s0></fA03><fA05><s2>21</s2></fA05><fA06><s2>4</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Spatially resolved photocurrent mapping of efficient organic solar cells fabricated on a woven mesh electrode</s1></fA08><fA11 i1="01" i2="1"><s1>KYLBERG (William)</s1></fA11><fA11 i1="02" i2="1"><s1>ARAUJO DE CASTRO (Fernando)</s1></fA11><fA11 i1="03" i2="1"><s1>CHABRECEK (Peter)</s1></fA11><fA11 i1="04" i2="1"><s1>GEIGER (Thomas)</s1></fA11><fA11 i1="05" i2="1"><s1>HEIER (Jakob)</s1></fA11><fA11 i1="06" i2="1"><s1>NICHOLSON (Patrick G.)</s1></fA11><fA11 i1="07" i2="1"><s1>NÜESCH (Frank)</s1></fA11><fA11 i1="08" i2="1"><s1>THEOCHAROUS (Evangelos)</s1></fA11><fA11 i1="09" i2="1"><s1>SONDEREGGER (Uriel)</s1></fA11><fA11 i1="10" i2="1"><s1>HANY (Roland)</s1></fA11><fA14 i1="01"><s1>Empa, Swiss Federal Institute for Materials Science and Technology, Laboratory for Functional Polymers, Überlandstrasse 129</s1><s2>8600 Dübendorf</s2><s3>CHE</s3><sZ>1 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ><sZ>10 aut.</sZ></fA14><fA14 i1="02"><s1>Sefar AG, Freibach</s1><s2>9425 Thai</s2><s3>CHE</s3><sZ>3 aut.</sZ><sZ>9 aut.</sZ></fA14><fA14 i1="03"><s1>National Physical Laboratory, Hampton Road, Teddington</s1><s2>Middlesex TW11 0LW</s2><s3>GBR</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ></fA14><fA20><s1>652-657</s1></fA20><fA21><s1>2013</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>26755</s2><s5>354000174777700260</s5></fA43><fA44><s0>0000</s0><s1>© 2013 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>18 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>13-0193168</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Progress in photovoltaics</s0></fA64><fA66 i1="01"><s0>GBR</s0></fA66><fC01 i1="01" l="ENG"><s0>Flexible organic photovoltaic devices may soon find applications in various fields, such as portable electronics or building-integrated photovoltaics, occupying market niches that are currently not covered by the prevailing photovoltaic technology based on silicon and other inorganic materials. For these applications, there is an urgent need to replace the commonly used indium tin oxide by transparent and electrically conductive materials that can be processed cost-effectively by large-area compatible printing and coating processes. Here, we fabricated P3HT/PCBM organic solar cells with a power conversion efficiency of 3.1% on a flexible, transparent and conductive woven fabric electrode. The electrode is produced by a roll-to-roll process and consists of a polymer-embedded fibre/metal wire grid. Metal wires protrude as little as 5 μm from the electrode plane, providing electrical contact points on a smooth surface suitable for thin film deposition. The use of spatially resolved photocurrent mapping experiments showed a high level of detailed information, with the unexpected indication that there probably exists a maximum in the cell performance versus mesh size opening and that woven fabric electrodes with largest geometrical open area do not necessarily perform better.</s0></fC01><fC02 i1="01" i2="X"><s0>001D06C02D1</s0></fC02><fC02 i1="02" i2="X"><s0>230</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Courant photoélectrique</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Photoelectric current</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Corriente fotoeléctrica</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Mappage</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Mapping</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Carta de datos</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Cellule solaire organique</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Organic solar 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l="SPA"><s0>Rejilla metálica</s0><s5>17</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Contact électrique</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Electric contact</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Contacto eléctrico</s0><s5>18</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Surface lisse</s0><s5>19</s5></fC03><fC03 i1="19" i2="X" l="ENG"><s0>Smooth surface</s0><s5>19</s5></fC03><fC03 i1="19" i2="X" l="SPA"><s0>Superficie lisa</s0><s5>19</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Evaluation performance</s0><s5>20</s5></fC03><fC03 i1="20" i2="X" l="ENG"><s0>Performance evaluation</s0><s5>20</s5></fC03><fC03 i1="20" i2="X" l="SPA"><s0>Evaluación prestación</s0><s5>20</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Silicium</s0><s2>NC</s2><s5>22</s5></fC03><fC03 i1="21" i2="X" l="ENG"><s0>Silicon</s0><s2>NC</s2><s5>22</s5></fC03><fC03 i1="21" i2="X" l="SPA"><s0>Silicio</s0><s2>NC</s2><s5>22</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Oxyde d'indium</s0><s5>23</s5></fC03><fC03 i1="22" i2="X" l="ENG"><s0>Indium oxide</s0><s5>23</s5></fC03><fC03 i1="22" i2="X" l="SPA"><s0>Indio óxido</s0><s5>23</s5></fC03><fC03 i1="23" i2="X" l="FRE"><s0>Matériau conducteur</s0><s5>24</s5></fC03><fC03 i1="23" i2="X" l="ENG"><s0>Conducting material</s0><s5>24</s5></fC03><fC03 i1="23" i2="X" l="SPA"><s0>Material conductor</s0><s5>24</s5></fC03><fC03 i1="24" i2="X" l="FRE"><s0>Matériau transparent</s0><s5>25</s5></fC03><fC03 i1="24" i2="X" l="ENG"><s0>Transparent material</s0><s5>25</s5></fC03><fC03 i1="24" i2="X" l="SPA"><s0>Material transparente</s0><s5>25</s5></fC03><fC03 i1="25" i2="X" l="FRE"><s0>Thiophène dérivé polymère</s0><s2>NK</s2><s5>26</s5></fC03><fC03 i1="25" i2="X" l="ENG"><s0>Thiophene derivative polymer</s0><s2>NK</s2><s5>26</s5></fC03><fC03 i1="25" i2="X" l="SPA"><s0>Tiofeno derivado polímero</s0><s2>NK</s2><s5>26</s5></fC03><fC03 i1="26" i2="X" l="FRE"><s0>Acide butyrique</s0><s2>NK</s2><s5>27</s5></fC03><fC03 i1="26" i2="X" l="ENG"><s0>Butyric acid</s0><s2>NK</s2><s5>27</s5></fC03><fC03 i1="26" i2="X" l="SPA"><s0>Butírico ácido</s0><s2>NK</s2><s5>27</s5></fC03><fC03 i1="27" i2="X" l="FRE"><s0>Ester</s0><s5>28</s5></fC03><fC03 i1="27" i2="X" l="ENG"><s0>Ester</s0><s5>28</s5></fC03><fC03 i1="27" i2="X" l="SPA"><s0>Ester</s0><s5>28</s5></fC03><fC03 i1="28" i2="3" l="FRE"><s0>Composé du fullerène</s0><s5>29</s5></fC03><fC03 i1="28" i2="3" l="ENG"><s0>Fullerene compounds</s0><s5>29</s5></fC03><fC03 i1="29" i2="3" l="FRE"><s0>Fibre polymère</s0><s5>30</s5></fC03><fC03 i1="29" i2="3" l="ENG"><s0>Polymer fibers</s0><s5>30</s5></fC03><fC03 i1="30" i2="X" l="FRE"><s0>Couche mince</s0><s5>31</s5></fC03><fC03 i1="30" i2="X" l="ENG"><s0>Thin film</s0><s5>31</s5></fC03><fC03 i1="30" i2="X" l="SPA"><s0>Capa fina</s0><s5>31</s5></fC03><fC03 i1="31" i2="X" l="FRE"><s0>ITO</s0><s4>INC</s4><s5>82</s5></fC03><fC03 i1="32" i2="X" l="FRE"><s0>Procédé roll-to-roll</s0><s4>CD</s4><s5>96</s5></fC03><fC03 i1="32" i2="X" l="ENG"><s0>Roll-to-roll process</s0><s4>CD</s4><s5>96</s5></fC03><fN21><s1>175</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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